Sunday 9 July 2017

3.9: Describe Experiments to Investigate the Effects of Changes in Surface Area of a Solid, Concentration of a Solution, Temperature and the Use of a Catalyst on the Rate of a Reaction



EFFECT OF SURFACE AREA OF A SOLID ON THE RATE OF REACTION:
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EFFECT OF SURFACE AREA ON THE RATE OF REACTION

Diagram showing the Process of Downwards Displacement to Investigate the Effect of Surface Area on the Rate of Reaction
METHOD:

  • Add dilute Hydrochloric acid into a conical flask
  • Use capillary tube to connect flask to a measuring cylinder placed upside down in a bucket of water (downwards displacement)
  • Add Calcium Carbonate chips into conical flask and close the bung
  • Measure the volume of gas produced in measuring cylinder in a fixed period of time
  • Repeat with different sizes of Calcium Carbonate chips (solid, crushed and powder)

RESULT:

  • As the surface area of solid increases, the rate of reaction will increase (positive correlation)
  • This is because as the surface area to volume ratio of a solid increases, more surface area particles are exposed to the other reactant
  • This allows more frequent successful collisions to occur, increasing the rate of reaction

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EFFECT OF CONCENTRATION OF A SOLUTION ON THE RATE OF REACTION:
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EFFECT OF CONCENTRATION ON THE RATE OF REACTION

Diagram Showing the Apparatus Needed to Investigating the Effect of Concentration on the Rate of Reaction
METHOD:

  • Measure 50 cm3 of Sodium Thiosulfate Solution in a Flask
  • Measure 5 cm3 of Dilute Hydrochloric Acid into a Measuring Cylinder
  • Draw a Cross on a Piece of Paper and Put it Underneath the Flask
  • Add the Acid into the Flask and Immediately Start the Stopwatch
  • Look Down at the Cross from Above and Stop the Stopwatch when the Cross can No Longer be Seen
  • Repeat Using Different Concentrations of Sodium Thiosulfate Solution (Mix Different Volumes of Sodium Thiosulfate Solution with Water to Dilute it)

RESULT:

  • Increase in the Concentration of a Solution, the Rate of Reaction will Increase
  • This is because there will be More Reactant Particles in a Given Volume, Allowing More Frequent and Successful Collisions, Increasing the Rate of Reaction

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EFFECT OF TEMPERATURE ON THE RATE OF REACTION:
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EFFECT OF TEMPERATURE ON THE RATE OF REACTION

Diagram Showing the Apparatus Needed to Investigate the Effect of Temperature on the Rate of Reaction
METHOD:

  • Dilute Hydrochloric Acid is Heated to Set Temperature Using a Water Bath
  • Add the Dilute Hydrochloric Acid into a Conical Flask
  • Add a Strip of Magnesium and Start the Stopwatch
  • Stop the Time when the Magnesium Fully Dissolves
  • Repeat at Different Temperatures and Compare Results

RESULT:

  • Increase in the Temperature, the Rate of Reaction will Increase
  • This is because the Particles will have More Kinetic Energy than the Required Activation Energy, therefore More Frequent and Successful Collisions will Occur, Increasing the Rate of Reaction

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EFFECT OF A CATALYST ON THE RATE OF REACTION:
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EFFECT OF CATALYST ON THE RATE OF REACTION

Diagram Showing the Apparatus Needed to Investigate the Effect of a Catalyst on the Rate of Reaction
METHOD:

  • Add Hydrogen Peroxide into a  Conical Flask
  • Use a Capillary Tube to Connect this Flask to a Measuring Cylinder Upside Down in a Bucket of Water (Downwards Displacement)
  • Add the Catalyst Manganese (IV) Oxide into the Conical Flask and Close the Bung
  • Measure the Volume of Gas Produced in a Fixed Time using the Measuring Cylinder
  • Repeat Experiment Without the Catalyst of Manganese (IV) Oxide and Compare Results

RESULT:

  • Using a Catalyst will Increase the Rate of Reaction
  • The Catalyst will Provide an Alternative Pathway Requiring Lower Activation Energy so More Colliding Particles will have the Necessary Activation Energy to React
  • This will Allow More Frequent and Successful Collisions, Increasing the Rate of Reaction

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