Monday 10 July 2017

1.58C: Describe Experiments to Investigate Electrolysis, Using Inert Electrode, of Molten Compounds (Including Lead (II) Bromide) and Aqueous Solutions (Including Sodium, Chloride, Dilute Sulfuric Acid and Copper (II) Sulphate) and to Predict the Products



ELECTROLYSIS: Decomposition of an ionic substance by passing an electric current through it
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ELECTROLYSIS OF LEAD (II) BROMIDE:
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ELECTROLYSIS OF LEAD (II) BROMIDE
Diagram showing the Electrolysis of Lead (II) Bromide
METHOD:

  • Add Lead (II) Bromide into a beaker and heat until molten, allowing ions to be free to move to conduct an electric charge
  • Add two Graphite rods as the electrodes and connect this to a power pack or battery
  • Turn on power pack or battery and allow Electrolysis to occur

REACTION AT ELECTRODES:
SOLUTION
PRODUCT AT POSITIVE ELECTRODE
PRODUCT AT NEGATIVE ELECTRODE
LEAD (II) BROMIDE ( PbBr2 )
Bromine   -   Br2
2Br -     -     2e-     →     Br2
Lead   -   Pb
Pb2+     +     2e-     →     Pb


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ELECTROLYSIS OF AQUEOUS SOLUTIONS:
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RULES:
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  • Aqueous Solutions will Always have Water ( H2O )
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Positive Electrode
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  • Either Oxygen or Non-Metal will be produced E.g Chlorine, Bromine, Nitrogen
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Negative Electrode
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  • Either Hydrogen or Metal will be produced
  • If Metal is above Hydrogen in Reactivity Series, Hydrogen will be produced
  • If Metal is below Hydrogen in Reactivity Series, Metal will be produced
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ELECTROLYSIS OF AQUEOUS SOLUTIONS
Diagram showing the Electrolysis of Aqueous Solutions
METHOD:

  • Add Aqueous Solution into a beaker
  • Add two Graphite rods as the electrodes and connect this to a power pack or battery
  • Turn on power pack or battery and allow Electrolysis to occur

REACTION AT ELECTRODES:
AQUEOUS SOLUTION
PRODUCT AT POSITIVE ELECTRODE
PRODUCT AT NEGATIVE ELECTRODE
SODIUM CHLORIDE ( NaCl )

Chlorine   -   Cl
2Cl-  -  2e-  →  Cl2
Hydrogen    -   H2
2H2O  +  2e-  →  H2  +  2OH-
DILUTE SULFURIC ACID ( H2SO4 )

Oxygen   -   O2
2H2O  -  4e-  →  O2  +  4H+
Hydrogen   -    H2
2H+  +  2e-  →  H2
COPPER (II) SULFATE ( CuSO4 )

Oxygen   -   O2
2H2O  -  4e-  →  O2  +  4H+
Copper   -   Cu
Cu2+  +  2e-  →  Cu

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